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Diya Aur Baati Hum
Diya Aur Baati Hum

Sandhya ji... Paani... (Page 11)

.Ami. IF-Sizzlerz
.Ami.
.Ami.

Joined: 10 January 2012
Posts: 11448

Posted: 07 September 2012 at 1:05am | IP Logged
Originally posted by June_Anne_Mary


there was a time when ppl used to run away when JAMLi duo enter forum. None was even dare to hit 'likes'. Comment toh badi door ki baat hai...LOL We'll start on the spot taang-pulling.. Now we both are very silent & obedient. No more badmaashi.Approve
Haan Haan. We're now such a "goody goody" ladkiya.. Wink Now everyone likes to comment in our threads..LOL Big smile You're so true once upon time nobody dared to enter wherever we stepped in whether it's MKD or our created threads..Embarrassed

dunia IF-Rockerz
dunia
dunia

Joined: 08 September 2008
Posts: 6505

Posted: 07 September 2012 at 1:06am | IP Logged
Originally posted by SAIBALROUTH

Originally posted by June_Anne_Mary

Originally posted by SAIBALROUTH

Originally posted by ami_dabh



@Bul-Bul
:- Yes Yes, We always rock in the pair. Oh so you're eager to attend chemistry lab..Confused But sorry I don't have any experiments to give you..Tu abhi munna hain..WinkROFL



This is not fair Ami Di Unhappy
I would have loved some small experiments, in order to gain some much needed experience LOL Wink
okay bul-bul go and do Friedel-Crafts acylation & explain what do u mean by Electrophilic aromatic substitution


Friedel-Crafts Acylation of Benzene

acylation of arenes

Reaction type: Electrophilic Aromatic Substitution

  • Overall transformation :  Ar-H toAr-COR(a ketone)
  • Named after Friedel and Crafts who discovered the reaction.
  • Reagent : normally the acyl halide (e.g. usually RCOCl) with aluminum trichloride, AlCl3, a Lewis acid catalyst.
  • Alternatively, the acid anhydride, i.e. (RCO)2O, can be used instead of the acyl halide.
  • The AlCl3 enhances the electrophilicity of the acyl halide by complexing with the halide.
  • Electrophilic species : the acyl cation or acylium ion (i.e. RCO + ) formed by the "removal" of the halide by the Lewis acid catalyst
  • The acylium ion is stabilised by resonance as shown below. This extra stability prevents the problems associated with the rearrangement of simple carbocations:
  • resonance stabilisation of the acylium ion
  • The reduction of acylation products can be used to give the equivalent of alkylation but avoids the problems of rearrangement
  • Friedel-Crafts reactions are limited to arenes as or more reactive than mono-halobenzenes
  • Other sources of acylium can also be used such as acid anhydrides with AlCl3


Electrophilic aromatic substitution is an organic reaction in which an atom that is attached to an aromatic system (usually hydrogen) is replaced by an electrophile. Some of the most important electrophilic aromatic substitutions are aromatic nitration, aromatic halogenation, aromatic sulfonation, and acylation and alkylating Friedel-Crafts reactions. Embarrassed


Kiya baat hai Saibal lagta hai mujhi apni chemistry class chor kar IF ki patshala mein Admission karni chahye..LOL

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SAIBALROUTH

.Ami. IF-Sizzlerz
.Ami.
.Ami.

Joined: 10 January 2012
Posts: 11448

Posted: 07 September 2012 at 1:10am | IP Logged
Originally posted by June_Anne_Mary

Whoa Amli, thanks 4 rewinding the video...Star Also, another one was the perfect open air DBC on Bajaj Chetak..ROFL.. Who can escape ROFLing..LOL
LOL ROFL ROFL ROFL ROFL Oh Gosh! I'm ROFLROFLROFL die on that so much..ROFLROFLROFL open air DBC on Bajaj chetak..ROFLROFLROFLROFL

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duniaSAIBALROUTH

maddy311 IF-Rockerz
maddy311
maddy311

Joined: 26 August 2011
Posts: 6861

Posted: 07 September 2012 at 3:25am | IP Logged
hehe thanks for the links guys. I will soon go through them in free timeWink

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SAIBALROUTH.Ami.

Brahmaputra IF-Sizzlerz
Brahmaputra
Brahmaputra

Joined: 12 February 2012
Posts: 13313

Posted: 07 September 2012 at 7:46am | IP Logged
Originally posted by dunia

Kiya baat hai Saibal lagta hai mujhi apni chemistry class chor kar IF ki patshala mein Admission karni chahye..LOL[/DIV]
haan haan...u can join our University. I shall deal Chemistry, Ami physics, Me again Biology(only homework doing instructions), History by Bul-bul, Literature by Maddy, Geoghraphy by Deebs, Communicative Studies by Juna, Love & Romance by Hema, Psychology by J, Microbiology & Genetics by Vishnu, Database again by Ami, Dendistry by Shehjar di, Defence Mechanisms by Naina, Crazy Creations by Farhana...etc great faculties we have..LOL..

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duniamaddy311.Ami.

.Ami. IF-Sizzlerz
.Ami.
.Ami.

Joined: 10 January 2012
Posts: 11448

Posted: 07 September 2012 at 7:50am | IP Logged
Originally posted by June_Anne_Mary

Originally posted by dunia

Kiya baat hai Saibal lagta hai mujhi apni chemistry class chor kar IF ki patshala mein Admission karni chahye..LOL[/DIV]
haan haan...u can join our University. I shall deal Chemistry, Ami physics, Me again Biology(only homework doing instructions), History by Bul-bul, Literature by Maddy, Geoghraphy by Deebs, Communicative Studies by Juna, Love & Romance by Hema, Psychology by J, Microbiology & Genetics by Vishnu, Database again by Ami, Dendistry by Shehjar di, Defence Mechanisms by Naina, Crazy Creations by Farhana...etc great faculties we have..LOL..
Why only Database?? Gimme charge of I.T world.. I'll rock n roll. Ferrari is aware about it.. We learn so many jasusi tricks..Big smile..

Ferrari how about our yesterday's ET kaand???LOL LOL LOL

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farhana874maddy311SAIBALROUTH

maddy311 IF-Rockerz
maddy311
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Joined: 26 August 2011
Posts: 6861

Posted: 07 September 2012 at 7:51am | IP Logged
jami ye literature kaun si bala haiROFL
Brahmaputra IF-Sizzlerz
Brahmaputra
Brahmaputra

Joined: 12 February 2012
Posts: 13313

Posted: 07 September 2012 at 7:57am | IP Logged
Haan, Amlu u take full charge of IT world...

Maddy- I dint get anything else 4 u. Can u take Palientology..Day Dreaming

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maddy311SAIBALROUTH.Ami.

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